Environment
Conservation Journal

"An International Journal Devoted to Conservation of Environment"

(A PEER REVIEWED JOURNAL)

ISSN: 2278-5124 (Online) :: ISSN: 0972-3099 (Print)

Environment
Conservation Journal

"An International Journal Devoted to Conservation of Environment"

(A PEER REVIEWED JOURNAL)

ISSN: 2278-5124 (Online) :: ISSN: 0972-3099 (Print)

Environment
Conservation Journal

"An International Journal Devoted to Conservation of Environment"

(A PEER REVIEWED JOURNAL)

ISSN: 2278-5124 (Online) :: ISSN: 0972-3099 (Print)

Environment
Conservation Journal

"An International Journal Devoted to Conservation of Environment"

(A PEER REVIEWED JOURNAL)

ISSN: 2278-5124 (Online) :: ISSN: 0972-3099 (Print)

Environment
Conservation Journal

"An International Journal Devoted to Conservation of Environment"

(A PEER REVIEWED JOURNAL)

ISSN: 2278-5124 (Online) :: ISSN: 0972-3099 (Print)

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Applications of Oxone in chemical kinetics, synthetic chemistry and environmental chemistry: A review

 Manila and Neha Bhatt

Department of Chemistry, K.G.C, Gurukula Kangri Vishwavidyalaya, Haridwar (U.K.), India

Abstract

Potassium monopersulphate (Oxone) is being widely used these days in various fields due to its unique properties which tend to make it an extremely viable option to be exercised. The oxidative nature of this compound is under study to extract the maximum benefits from this compound amongst which chemical, synthetic and environmental studies are prominent fields in which a steady research is underway. The objective of this review is to provide valuable information on various applications of oxone which are coming into light due to the diverse research work being carried out on it.

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F.Javier Rivas, Ruth Garcia, Juan F. Garcia-Araya, Olga Gimeno, 2017. “Promoted wet air oxidation of polynuclear aromatic hydrocarbons”, Department de Ingenieria Quimica y Quimica Fisica, Edificio Jose Luis Sotelo, Facultad de Ciencias, Universidad de Extremadura, Av. Elvas S/N, 06071 Badajoz, Spain.

Iturmendi, A., Iglesias, M., Munárriz, J., Polo, V., Pérez-Torrente, J.J., Oro, L.A., 2017. “Efficient preparation of carbamates by Rh-catalysed oxidative carbonylation: unveiling the role of the oxidant”, Departamento Química Inorgánica-ISQCH, Universidad de Zaragoza-CSIC, Zaragoza, Spain; Departamento Química Física, Instituto de Biocomputación y Física de Sistemas Complejos (BIFI), Universidad de Zaragoza, Zaragoza, Spain;  King Fahd University of Petroleum & Minerals (KFUPM), Dhahran, Saudi Arabia; Chemical Communications; 53(2):404-407.

Iyer, S.K., Munusamy, S., Muralidharan, V.P., 2017. “Direct oxidative cascade cyclisation of 2-aminobenzoic acid and arylaldehydes to aryl 4H-3,1-benzoxazin-4-ones with oxone”, Tetrahedron letters, 58(6): 520-523.

Javier Rivas, Olga Gimeno, Maria Carbajo and Teresa Borralho, 2009. “Catalytic decomposition of potassium monopersulfate. Influence of variables”, World academy of science, engineering and technology 57 2009.

Jia-Cheng E. Yang, Baoling Yuan, Hao-Jie Cui, Shaobin Wang, Ming-Lai Fu, 2017. “Modulating oxone-MnOx/silica catalytic systems towards ibuprofen degradation: Insights into system effects, reaction kinetics and mechanisms’’,  Applied Catalysis B: Environmental 205:327-339.

Lam, S.H, Gong, H., Chu,W., Lin, A.Y.-C., 2017. “Ibuprofen degradation and toxicity evolution during Fe2+/Oxone/UV process”, Department of Civil and Environmental Engineering, The Hong Kong Polytechnic University, Hung Hom, Kowloon, Hong Kong; Graduate Institute of Environmental Engineering, National Taiwan University, Taipei, Taiwan; Chemosphere; 167:415-421.

Moghaddam, N.J., Najafpour, M.M., 2017. “An efficient nickel oxides/nickel structure for water oxidation: a new strategy”,  Department of Chemistry, Institute for Advanced Studies in Basic Sciences (IASBS), Zanjan, Iran;  Center of Climate Change and Global Warming, Institute for Advanced Studies in Basic Sciences (IASBS), Zanjan, Iran; New Journal of Chemistry; 41(5):1909-1913.

Moorthy, J.N., Mishra, A.K., 2017. “Mechanochemical catalytic oxidations in the solid state with: In situ -generated modified IBX from 3,5-di- tert-butyl-2-iodobenzoic acid (DTB-IA)/Oxone”, Organic Chemistry Frontiers, 4( 3):343-349.

Raviteja, P., Swamy, T., Srikanth, G., Reddy, B.V.S., Ravinder, V., 2016.  “RuCl3/Oxone: An efficient combination for the synthesis of 3-aryl-[1,2,4]triazolo[4,3-a]pyridines from 2-(2-arylidenehydrazinol)pyridines”; Department of Chemistry, Kakatiya University, Warangal, Telangana State, India; Centre for Semiochemicals, CSIR-Indian Institute of Chemical Technology, Hyderabad, India; Tetrahedron Letters; 57(50):5596-5598.

Reddy, K.R., Kannaboina, P., Das, P., 2017. “Palladium-Catalyzed Chemoselective Switch: Synthesis of a New Class of Indenochromenes and Pyrano[2,3-c]carbazoles”; Medicinal Chemistry Division CSIR-Indian Institute of Integrative Medicine Canal Road Jammu- 180001 India;  Academy of Scientific and Innovative Research (AcSIR) New Delhi- 110025 India; Asian Journal of Organic Chemistry.

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Sharninghausen, L.S., Michaelos, T.K., Lant, H.M.C., Craig, S.M., Menges, F.S., Mercado, B.Q., Brudvig, G.W., Crabtree, R.H., 2016. “Catalytic Oxygen Evolution from Manganese Complexes with an Oxidation-Resistant N,N,O-Donor Ligand”, Department of Chemistry, Yale University, 225 Prospect Street, New Haven, CT, United States; ChemPlusChem; 81(10):1129-1132.

Shu, H.-Y., Huang, S.-W., Tsai, M.-K., 2016. “Comparative study of acid blue 113 wastewater degradation and mineralization by UV/persulfate and UV/Oxone processes”, Institute of Environmental Engineering, Hungkuang University, Taichung, Taiwan; Desalination and Water Treatment; 57(60): 29517-29530.

Simeonov, S.P., Vicente, A.I., Coelho, J.A.S, Lazarova, H.I., Popova, M.D., Afonso, C.A.M., 2017. “ Oxidation of 5-Chloromethylfurfural (CMF) to 2,5-Diformylfuran (DFF)”, Research Institute for Medicines (iMed.ULisboa), Faculty of Pharmacy, Universidade de Lisboa, Av. Prof. Gama Pinto, Lisboa, Portugal; Institute of Organic Chemistry, Centre of Phytochemistry Bulgarian Academy of Sciences, Acad. G. Bonchev str., bl. 9, Sofia, Bulgaria; 22(2) Article number 329.

Solís, R.R., Rivas, F.J., Tierno, M., 2016. “Monopersulfate photocatalysis under 365 nm radiation. Direct oxidation and monopersulfate promoted photocatalysis of the herbicide tembotrione”; Department of Chemical Engineering, Physical Chemistry, University of Extremadura, Av. Elvas s/n, Badajoz, Spain; University Institute of Water Research, Climate Change and Sustainability, IACYS. University of Extremadura, Av. Elvas s/n, Badajoz, Spain; Journal of Environmental Management; (181):385-394.

Srinivas, M., Devi, L.G., ArunaKumari, M.L., 2016. “Heterogeneous advanced photo- Fenton process using peroxymonosulfate and peroxydisulfate in presence of zero valent metallic iron:A comparative study with hydrogen peroxide photo-Fenton process”; Department of Post Graduate Studies in Chemistry, Central College City Campus, Bangalore University, Dr. Ambedkar Street, Bangalore, India; Journal of Water Process Engineering; 13: 117-126.

Sriramoju, V., Jillella, R., Kurva, S., Madabhushi, S., 2017. “A study on reactions of an alkynylsilane with oxone-KX (X = Cl, Br, I) and its one-pot transformation into an amide/ester”, Fluoroorganics Division, CSIR-Indian Institute of Chemical Technology, Hyderabad, India; Chemistry Letters; 46(4):560-562.

Wacławek, S., Antoš, V., Hrabák, P., Černík, M., 2016. “Remediation of hexachlorocyclohexanes by cobalt-mediated activation of peroxymonosulfate”;Centre for Nanomaterials, Advanced Technologies and Innovation, Technical University of Liberec, Studentská 1402/2, Liberec 1, Czech Republic; Desalination and Water Treatment; 57(54):26274-26279.

Xiao, K., Chen, Y., Jiang, X., Yang, Q., Seow, W.Y.,  Zhu, W., Zhou, Y., 2017. ‘‘Variations in physical, chemical and biological properties in relation to sludge dewaterability under Fe (II) – Oxone conditioning’’ , Advanced Environmental Biotechnology Centre, Nanyang Environment and Water Research Institute, Nanyang Technological University, 1 Cleantech Loop, Singapore, Singapore; School of Civil and Environmental Engineering, Nanyang Technological University, 50 Nanyang Avenue, Singapore, Singapore; (109):13-23.

 Yoshimura, A., Soldatova, N., Postnikov, P., Troyan, A.A., Yusubov, M.S., Zhdankin, V.V, 2016. “Mild and efficient synthesis of iodylarenes using Oxone as oxidant”; The Tomsk Polytechnic University, Tomsk, Russian Federation; Department of Chemistry and Biochemistry, University of Minnesota Duluth, Duluth, MN, United States; Tetrahedron Letters; 57( 37):4254-4256.

Yusubov, M.S., Soldatova, N., Postnikov, P., Kukurina, O., Zhdankin, V.V., Yoshimura, A., Wirth, T. , 2017.  “Facile One-Pot Synthesis of Diaryliodonium Salts from Arenes and Aryl Iodides with Oxone”, Tomsk Polytechnic University and Siberian State Medical University, Tomsk, Russian Federation; Department of Chemistry and Biochemistry, University of Minnesota Duluth, Duluth, MN, United States; School of Chemistry, Cardiff University, Park Place, Main Building, Cardiff, United Kingdom; 6(1):18-20

Manila and Neha, B. (2017). Applications of Oxone in chemical kinetics, synthetic chemistry and environmental chemistry: a review. Environment Conservation Journal18(3), 135-140.

:https://doi.org/10.36953/ECJ.2017.18317

Received: 29.05.2017

Revised: 29.07.2017

Accepted: 11.08.2017

First Online: 21.12. 2017

:https://doi.org/10.36953/ECJ.2017.18317

MANUSCRIPT STATISTICS

Publisher Name:  Action for Sustainable Efficacious Development and Awareness (ASEA)

Print : 0972-3099

Online :2278-5124